Jornal de Técnicas Analíticas e Bioanalíticas

Abstrato

Sodium Dodecyl Sulphate/Poly(Brilliant Blue)/Multi Walled Carbon Nanotube Modified Carbon Paste Electrode for the Voltammetric Resolution of Dopamine in the Presence of Ascorbic Acid and Uric Acid

Ganesh PS and Kumara Swamy BE

Sodium dodecyl sulphate/poly(brilliant blue)/multi walled carbon nanotube modified carbon paste electrode was fabricated for the electroanalysis of dopamine in the presence of ascorbic acid and uric acid in phosphate buffer solution of pH 7.4. The key parameters such as sensitivity, selectivity, antifouling property and stability were achievedby the modified electrode. The redox peaks obtained at modified electrode shows good electrocatalytic activity towards the oxidation of dopamine. From the effect of scan rateand concentration the electrode phenomenon was confirmed to be adsorption-controlled process. The lower limit of detection of dopamine was 2.69 × 10-7M, and the simultaneous analysis shows a good result with peak to peak separation between dopamine and other two analytes ascorbic acid and uric acid by both cyclic voltammetry and differential pulse voltammetric techniques.